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Metalloheterocykliske forbindelser

Organiske forbindelser, der indeholder en eller flere heterocykliske grupper, der indeholder et metalelement; heterocykler er ringe, der indeholder atomer fra to eller flere typer grundstoffer.

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1

1,2-bis((2S,5S)-2,5-diethylphospholan)benzen(cyclooctadien)rhodium(I)tetrafluorborat, 97 %, Thermo Scientific Chemicals

CAS: 213343-64-7 Molekylær formel: C30H48BF4P2Rh Molekylvægt (g/mol): 660.37 MDL nummer: MFCD01862465 InChI nøgle: DSYBEQKPSKLNMC-RTXTXWNLNA-N Synonym: s,s-et-duphos-rh,+-1,2-bis 2s,5s-2,5-diethylphospholano benzene cyclooctadiene rhodium i tetrafluoroborate,+-1,2-bis 2s,5s-2,5-diethylphospholano benzene cyclooctadiene rhodium l tetrafluoroborate PubChem CID: 11006841 SMIL: [Rh+].F[B-](F)(F)F.C1C\C=C/CC\C=C/1.CC[C@H]1CC[C@H](CC)P1C1=C(C=CC=C1)P1[C@@H](CC)CC[C@@H]1CC

MDL nummer MFCD01862465
PubChem CID 11006841
Molekylvægt (g/mol) 660.37
CAS 213343-64-7
Synonym s,s-et-duphos-rh,+-1,2-bis 2s,5s-2,5-diethylphospholano benzene cyclooctadiene rhodium i tetrafluoroborate,+-1,2-bis 2s,5s-2,5-diethylphospholano benzene cyclooctadiene rhodium l tetrafluoroborate
SMIL [Rh+].F[B-](F)(F)F.C1C\C=C/CC\C=C/1.CC[C@H]1CC[C@H](CC)P1C1=C(C=CC=C1)P1[C@@H](CC)CC[C@@H]1CC
InChI nøgle DSYBEQKPSKLNMC-RTXTXWNLNA-N
Molekylær formel C30H48BF4P2Rh
2

(2S,5S)-1-(2-(1,3-dioxolan-2-yl)phenyl)-2,5-diethylphospholan, 97 %, Thermo Scientific™

CAS: 1314246-02-0 Molekylær formel: C17H25O2P Molekylvægt (g/mol): 292.36 MDL nummer: MFCD09265099 InChI nøgle: UKBFKBMQNUOKTD-UHFFFAOYNA-N Synonym: 2s,5s---1-2-1,3-dioxolan-2-yl phenyl-2,5-diethylphospholane,s,s-et-rajphos,2-2-2s,5s-2,5-diethyl-1-phospholano phenyl 1,3-dioxolane,2-2-2s,5s-2,5-diethylphospholan-1-yl phenyl-1,3-dioxolane,trans-1-2-1,3-dioxolan-2-yl phenyl-2,5-diethylphospholane,2s,5s-1-2-1,3-dioxolan-2-yl phenyl-2,5-diethylphospholane,2s,5s---1-2-1,3-dioxolan-2-yl phenyl-2,5-diethylphospholane, kanata purity PubChem CID: 16218309 IUPAC navn: 1-[2-(1,3-dioxolan-2-yl)phenyl]-2,5-diethylphospholan SMIL: CCC1CCC(CC)P1C1=CC=CC=C1C1OCCO1

MDL nummer MFCD09265099
PubChem CID 16218309
Molekylvægt (g/mol) 292.36
CAS 1314246-02-0
Synonym 2s,5s---1-2-1,3-dioxolan-2-yl phenyl-2,5-diethylphospholane,s,s-et-rajphos,2-2-2s,5s-2,5-diethyl-1-phospholano phenyl 1,3-dioxolane,2-2-2s,5s-2,5-diethylphospholan-1-yl phenyl-1,3-dioxolane,trans-1-2-1,3-dioxolan-2-yl phenyl-2,5-diethylphospholane,2s,5s-1-2-1,3-dioxolan-2-yl phenyl-2,5-diethylphospholane,2s,5s---1-2-1,3-dioxolan-2-yl phenyl-2,5-diethylphospholane, kanata purity
SMIL CCC1CCC(CC)P1C1=CC=CC=C1C1OCCO1
IUPAC navn 1-[2-(1,3-dioxolan-2-yl)phenyl]-2,5-diethylphospholan
InChI nøgle UKBFKBMQNUOKTD-UHFFFAOYNA-N
Molekylær formel C17H25O2P
3

(2S,5S)-1-(2-(1,3-dioxolan-2-yl)phenyl)-2,5-dimethylphospholan, 97 %, Thermo Scientific™

CAS: 695816-47-8 Molekylær formel: C15H21O2P Molekylvægt (g/mol): 264.3 InChI nøgle: JAKXTLMNIHPLEU-RYUDHWBXSA-N Synonym: 2s,5s-+-1-2-1,3-dioxolan-2-yl phenyl-2,5-dimethylphospholane,2s,5s-1-2-1,3-dioxolan-2-yl phenyl-2,5-dimethylphospholane,s,s-me-rajphos,2-2-2s,5s-2,5-dimethylphospholan-1-yl phenyl-1,3-dioxolane,2s,5s-+-1-2-1,3-dioxolan-2-yl phenyl-2,5-dimethylphospholane, kanata purity,1-2-1,3-dioxolane-2-yl phenyl-2beta,5alpha-dimethyltetrahydro-1h-phosphole,2-2-2s,5s-2,5-dimethyl-1-phospholano phenyl 1,3-dioxolane, min PubChem CID: 16218307 IUPAC navn: 2-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]phenyl]-1,3-dioxolan SMIL: CC1CCC(P1C2=CC=CC=C2C3OCCO3)C

PubChem CID 16218307
Molekylvægt (g/mol) 264.3
CAS 695816-47-8
Synonym 2s,5s-+-1-2-1,3-dioxolan-2-yl phenyl-2,5-dimethylphospholane,2s,5s-1-2-1,3-dioxolan-2-yl phenyl-2,5-dimethylphospholane,s,s-me-rajphos,2-2-2s,5s-2,5-dimethylphospholan-1-yl phenyl-1,3-dioxolane,2s,5s-+-1-2-1,3-dioxolan-2-yl phenyl-2,5-dimethylphospholane, kanata purity,1-2-1,3-dioxolane-2-yl phenyl-2beta,5alpha-dimethyltetrahydro-1h-phosphole,2-2-2s,5s-2,5-dimethyl-1-phospholano phenyl 1,3-dioxolane, min
SMIL CC1CCC(P1C2=CC=CC=C2C3OCCO3)C
IUPAC navn 2-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]phenyl]-1,3-dioxolan
InChI nøgle JAKXTLMNIHPLEU-RYUDHWBXSA-N
Molekylær formel C15H21O2P
4

9-Borabicyclo[3.3.1]nonane, 0.5M solution in THF, AcroSeal™

CAS: 280-64-8 | C8H15B | 122.02 g/mol

MDL nummer MFCD00074742
Kemisk navn eller materiale 9-Borabicyclo[3.3.1]nonane
Specifik vægtfylde 0.884
Sundhedsfare 3 GHS P Statement
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
Handle under inert gas.
Protect from moisture
Sundhedsfare 2 GHS H Statement
In contact with water releases flammable gases.
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
May cause respiratory irritation.
Suspected of causing cancer.
May form explo
Sundhedsfare 1 GHS-signalord: Fare
Formel vægt 122.02
Opløselighedsinformation Solubility in water: reacts
CAS min % 92.49
IUPAC navn 9$l^{2}-borabicyclo[3.3.1]nonan
PubChem CID 6327450
Molekylvægt (g/mol) 122.02
Tæthed 0.8840g/mL
Fieser 02,31; 03,24; 04,41; 05,46; 06,62; 07,29; 08,47; 09,57; 10,48; 11,68; 13,92; 14,52; 15,43; 17,49; 01,732; 04,356
EINECS nummer 206-000-9
CAS 109-99-9
Synonym 9-borabicyclo 3.3.1 nonane,9-borabicyclo 3.3.1 nonan,9-borabicyclo 3,3,1 nonane,9$l^ 2-borabicyclo 3.3.1 nonane,1s,5s-9-borabicyclo 3.3.1 nonane,monomer; 21205-91-4 dimer,9-borabicyclo 3.3.1 nonane,9-bbn,intetrahydrofuran
SMIL [B]1C2CCCC1CCC2
Flammepunkt −17°C
InChI nøgle AMKGKYQBASDDJB-UHFFFAOYSA-N
Molekylær formel C8H15B
CAS Max % 93.86
5

1,1'-bis((2R,5R)-2,5-diisopropylphospholan)ferrocen(cyclooctadien)rhodium(I)tetrafluorborat, 97 %, Thermo Scientific™

CAS: 849773-97-3 Molekylær formel: C38H60BF4FeP2Rh Molekylvægt (g/mol): 824.40 MDL nummer: MFCD15144872 InChI nøgle: MFSWTFGIDMKBOY-UHFFFAOYNA-N Synonym: 1,1 inverted exclamation marka-bis 2r,5r-2,5-diisopropylphospholano ferrocene cyclooctadiene rhodium i tetrafluoroborate PubChem CID: 71310759 IUPAC navn: (1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-cyclopenta-2,4-dien-1-yl-2,5-di(propan-2-yl)phospholane;iron(2+);rhodium;tetrafluoroborate SMIL: [Fe].[Rh+].F[B-](F)(F)F.C1C\C=C/CC\C=C/1.CC(C)[C@H]1CC[C@H](C(C)C)P1c1cccc1.CC(C)[C@H]1CC[C@H](C(C)C)P1c1cccc1

MDL nummer MFCD15144872
PubChem CID 71310759
Molekylvægt (g/mol) 824.40
CAS 849773-97-3
Synonym 1,1 inverted exclamation marka-bis 2r,5r-2,5-diisopropylphospholano ferrocene cyclooctadiene rhodium i tetrafluoroborate
SMIL [Fe].[Rh+].F[B-](F)(F)F.C1C\C=C/CC\C=C/1.CC(C)[C@H]1CC[C@H](C(C)C)P1c1cccc1.CC(C)[C@H]1CC[C@H](C(C)C)P1c1cccc1
IUPAC navn (1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-cyclopenta-2,4-dien-1-yl-2,5-di(propan-2-yl)phospholane;iron(2+);rhodium;tetrafluoroborate
InChI nøgle MFSWTFGIDMKBOY-UHFFFAOYNA-N
Molekylær formel C38H60BF4FeP2Rh