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  8. 2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water

2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water

Artikelnummer. 11334316
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Mængde:
1 g
5 g
Pakningsstørrelse:
1g
5g
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Artikelnummer. 11334316 Leverandør Thermo Scientific Alfa Aesar Leverandørnr. L19383.06
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Beskrivelse

CAS: 36982-84-0 | C15H23N3O2S | 309.428 g/mol

2,4,6-Triisopropylbenzenesulfonyl azide is used as a reagent for diazo transfer to ketones, e.g. under phase-transfer conditions, giving better yields of sterically-hindered ?-diazo ketones than other methods. It is also used for azide transfer to potassium enolates (KHMDS) to form the ?-azido derivatives.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2,4,6-Triisopropylbenzenesulfonyl azide is used as a reagent for diazo transfer to ketones, e.g. under phase-transfer conditions, giving better yields of sterically-hindered ɑ-diazo ketones than other methods. It is also used for azide transfer to potassium enolates (KHMDS) to form the ɑ-azido derivatives.

Solubility
Insoluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature is 2 - 8°C.
TRUSTED_SUSTAINABILITY

Kemiske identifikatorer

CAS 36982-84-0
Molekylær formel C15H23N3O2S
Molekylvægt (g/mol) 309.428
MDL nummer MFCD00859286
InChI nøgle AEMWUHCKKDPRSK-UHFFFAOYSA-N
Synonym 2,4,6-triisopropylbenzenesulfonyl azide, 2,4,6-triisopropylbenzene-sulfonyl azide, trisyl azide, 2,4,6-triisopropylbenzene-sulfonyl azide,, benzenesulfonyl azide, 2,4,6-tris 1-methylethyl, 2,4,6-triisopropyl-benzenesulfonyl azide, n-diazo-2,4,6-triisopropyl-benzenesulfonamide, 2,4,6-tris 1-methylethyl-benzenesulfonyl azide, 2,4,6-triisopropylbenzenesulfonyl azide, stab. with ca water, trisyl azide solution
PubChem CID 371707
IUPAC navn N-diazo-2,4,6-tri(propan-2-yl)benzenesulfonamide
SMIL CC(C)C1=CC(=C(C(=C1)C(C)C)S(=O)(=O)N=[N+]=[N-])C(C)C

Tekniske data

Kemisk navn eller materiale 2,4,6-Triisopropylbenzenesulfonyl azide
Navn note stabilized with ≈10% water
Smeltepunkt 40°C to 44°C
Mængde 5 g
Opløselighedsinformation Insoluble in water.
Formel vægt 309.43
Procent renhed 98%

RUO – Research Use Only

Produkttitel
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