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  7. Zirconium(IV) chloride, 98%, cont. 1-2% hafnium(IV) chloride, Thermo Scientific Chemicals

Zirconium(IV) chloride, 98%, cont. 1-2% hafnium(IV) chloride, Thermo Scientific Chemicals

Artikelnummer. 11383716
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Mængde:
50 g
250 g
Pakningsstørrelse:
250g
50g
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Artikelnummer. 11383716 Leverandør Thermo Scientific Alfa Aesar Leverandørnr. L14891.30
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Beskrivelse

Zirconium(IV) chloride catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyl­tin hydride. It is used as a superior catalyst for the fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures. In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Zirconium(IV) chloride catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyl­tin hydride. It is used as a superior catalyst for the fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures. In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde.

Solubility
Reacts with water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Handle and store under inert gas. It is sensitive to moisture. Incompatible with bases and oxidizing agents.
TRUSTED_SUSTAINABILITY

Kemiske identifikatorer

CAS 10026-11-6
Molekylær formel ZrCl4
MDL nummer MFCD00011306
Synonym Zirconium tetrachloride

Tekniske data

Kemisk navn eller materiale Zirconium(IV) chloride
Smeltepunkt 331°C (sublimation)
Mængde 250 g
Assay Procent Noter cont. 1 to 2% hafnium(IV) chloride
FN nummer UN2503
Merck Index 14,10174
Opløselighedsinformation Reacts with water.
Formel vægt 233.03
Procent renhed 98%
Følsomhed Moisture sensitive
Tæthed 2.803
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