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Diisobutylaluminum hydride, 1M solution in toluene

Artikelnummer. 15460837
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Mængde:
100 mL
Pakningsstørrelse:
100ml
Denne vare kan ikke returneres. Se returpolicy
Regulatory: This product is an isolated intermediate transported in accordance with Regulation (EC) 1907/2006 (REACH). All customers must complete a declaration before delivery.

Artikelnummer. 15460837

Brand: Thermo Scientific Alfa Aesar L14718.AE

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Denne vare kan ikke returneres. Se returpolicy
Regulatory: This product is an isolated intermediate transported in accordance with Regulation (EC) 1907/2006 (REACH). All customers must complete a declaration before delivery.

Beskrivelse

CAS: 1191-15-7 | C8H19Al

Diisobutylaluminum hydride reduces chiral ?-silyloxy esters to the corresponding enantiomerically-pure hydroxy aldehydes. I t is used in Pd-catalyzed reductive debromination of secondary alkyl bromides, O-Debenzylation and ring opening of perbenzylated furanosides and convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diisobutylaluminum hydride reduces chiral ɑ-silyloxy esters to the corresponding enantiomerically-pure hydroxy aldehydes. I t is used in Pd-catalyzed reductive debromination of secondary alkyl bromides, O-Debenzylation and ring open
TRUSTED_SUSTAINABILITY

Tekniske data

Kemisk navn eller materiale Diisobutylaluminum hydride
CAS 1191-15-7
Tæthed 0.805
Kogepunkt ∼110°C
Flammepunkt 4°C (40°F)
Molekylær formel C8H19Al
Lineær formel [(CH3)2CHCH2]2AlH
MDL nummer MFCD00008928
Mængde 100 mL
FN nummer UN3399
Beilstein 4123663
Følsomhed Moisture sensitive
Synonym DIBAH; DIBAL-H
Opløselighedsinformation Reacts with water.
Formel vægt 142.22
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