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  7. Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4, Thermo Scientific™

Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4, Thermo Scientific™

Artikelnummer. 15143726
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Artikelnummer. 15143726 Leverandør Thermo Scientific Alfa Aesar Leverandørnr. L13961.AE
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Beskrivelse

This Thermo Scientific brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific.

Applications
Borane-tetrahydrofuran complex is an important reagent used in the reduction of certain functional groups viz. aldehyde, ketone, carboxylic acid, amide, oxime, imine and nitrile. It is also used as hydro borating agent. It acts as a borane source for oxazaborolidine catalyzed asymmetric reductions. It is utilized to reduce nylon surface amide groups to secondary amines.

Solubility
Miscible and reacts violently with water.

Notes
Air and moisture sensitive. Forms explosive peroxides in contact with air. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents and alcohols. On hydrolysis, it forms hydrogen and boric acid.
TRUSTED_SUSTAINABILITY

Kemiske identifikatorer

CAS 14044-65-6
Molekylær formel C4H11BO
Molekylvægt (g/mol) 85.94
MDL nummer MFCD00012429
InChI nøgle RMCYTHFAWCWRFA-UHFFFAOYSA-N
Synonym borane-tetrahydrofuran complex, tetrahydrofuran borane, bh3.thf, borane tetrahydrofuran complex solution, borane-d3-thf complex solution, borane-tetrahydrofuran, unii-5ear4err1l, oxolane borane, boron; oxolane, borane thf
PubChem CID 11062302
IUPAC navn boron;oxolane
SMIL B.C1CCOC1

Tekniske data

Kemisk navn eller materiale Borane-tetrahydrofuran Complex
Navn note stabilized with 5mmol NaBH4
Tæthed 0.878
Flammepunkt −21°C (−8°F)
Lineær formel BH3/(CH2)4O
Mængde 100 mL
FN nummer UN3148
Beilstein 3668402
Følsomhed Air and moisture sensitive
Opløselighedsinformation Miscible and reacts violently with water.
Formel vægt 85.94
Koncentration eller sammensætning (efter analyt eller komponenter) 1M soln. in THF
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