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1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%

Artikelnummer. 11369717
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Mængde:
50 mg
Pakningsstørrelse:
50mg
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Artikelnummer. 11369717 Leverandør Thermo Scientific Alfa Aesar Leverandørnr. 042057.MF
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Beskrivelse

CAS: 64536-78-3 | C31H50F6IrNP2 | 804.90 g/mol

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

 
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Tekniske data

Kemisk navn eller materiale 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
CAS 64536-78-3
Smeltepunkt 175°C (decomposition)
Molekylær formel C31H50F6IrNP2
MDL nummer MFCD00075097
Mængde 50 mg
Følsomhed Moisture sensitive
Synonym crabtree's catalyst, unii-816 rs2nbpn, 816 rs2nbpn, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium hexafluorophosphate, iridium i hexafluorophosphate, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium i hexafluorophosphate, tricyclohexylphosphine 1,5-cyclooctadiene pyridine iridium i hexafluorophosphate, felkin-crabtree catalyst, crabtree's catalyst mi, crabtree's catalyst hexafluorophosphate
Opløselighedsinformation Slightly soluble in acetone,dichloromethane,ethanol and diethyl ether; Insoluble aq. soln..
InChI nøgle UJXHUUQZACSUOG-KJWGIZLLSA-N
SMIL [Ir+].C1=CC=NC=C1.F[P-](F)(F)(F)(F)F.C1C\C=C/CC\C=C/1.C1CCC(CC1)P(C1CCCCC1)C1CCCCC1
IUPAC navn iridium(1+) (1Z,5Z)-cycloocta-1,5-diene hexafluoro-λ⁵-phosphanuide pyridine tricyclohexylphosphane
Molekylvægt (g/mol) 804.90
PubChem CID 5702647
Formel vægt 804.89
Procent renhed 99%
Fysisk form Crystalline Powder
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